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IMPORTANT VARIABLES
In general, the most important variables that affect
adsorption are:
Temperature, P.H., and the size of the particle.
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TEMPERATURE
A higher temperature generally makes reaching equilibrium faster;
yet, the amount of adsorbed impurity is lower. That means that if
time were not important, more adsorption could be achieved at a lower
temperature; rarely practical at an industrial level, so increasing
the temperature -when possible- is generally beneficial.
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PH
Many compounds that originate color vary in structure and color when
the PH changes. In most of the cases discoloration to a lower PH is
more efficient because of two reasons:
- Compounds that generate color are generally highly dependent on
the PH, becoming less intense at a lower PH.
- Adsorption is possibly more efficient at a lower PH. When you are
not sure about the behavior, it is better to modify the PH and find
an activated carbon with a PH that is close to that of the process.
- CARBON
PARTICLE SIZE
As mentioned before, the carbon area is internal and consequently the
size of the particle does not have any effect on the adsorption capacity
of the carbon itself. Yet, it does affect the velocity to reach the
equilibrium.
For example: On a certain application, several hours of contact might
be needed when using granular carbon in order to get the same results
that might have been obtained using powdered carbon during a 30 minute
contact. The disadvantages of using a smaller particle are:
- With granular carbon: A higher pressure drop
- With powdered carbon: Less filtration capacity.
Carbon
Purity: ashes
Ashes
are inorganic compounds present in the raw material from which the activated
carbon was produced and that did not volatilize during the activation
process.
The ash content is associated to the quality of a carbon; yet, this is
not entirely so because what is important is the part of the ashes that
is soluble in the product that is being purified.
There
are many applications in which ashes are not important; nevertheless,
there are some processes in which the presence of inorganic compounds,
for example, calcium, magnesium, and iron can cause an unwanted reaction.
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Also
visit:
[ The
Mystery of Activated Carbon
| Activation
Process |
Classification of Activated
Carbon |
Liquid Fase Purification | Gas
Fase Purification ]
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